Damit... I just dont.. get it..
In photoshop the picture looks perfect... as soon as i export a PNG - it gets ten times more saturated and a million times darker!! and if i artificially raise the midtones before exporting -> the contrast gets all f*cked up. Very weird. :/

Once again.. you must view the picture in complete darkness to be able to see anything on the screen :)

Photoshop
Wacom
Some color reference from Alice: Madness Returns.
About 3 hours.